MCQMediumJEE 2024Isothermal & Adiabatic Processes

JEE Physics 2024 Question with Solution

Two thermodynamical processes are shown in the figure. The molar heat capacity for process AA and BB are CAC_A and CBC_B. The molar heat capacity at constant pressure and constant volume are represented by CPC_P and CVC_V respectively. Choose the correct statement:

  • A

    CB=, CA=0C_B = \infty,\ C_A = 0

  • B

    CA=0 and CB=C_A = 0\ \text{and}\ C_B = \infty

  • C

    CP>CA=CB=CVC_P > C_A = C_B = C_V

  • D

    CA>CP>CV>CBC_A > C_P > C_V > C_B

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: Two thermodynamical processes AA and BB are identified from a logP\log P vs. logV\log V figure. Find: the correct relation among CAC_A, CBC_B, CPC_P and CVC_V.

From the solution, process AA has slope tan1γ\tan^{-1}\gamma where

γ=CPCV\gamma = \frac{C_P}{C_V}

so process AA is adiabatic, using

PVγ=constantPV^{\gamma} = \text{constant}

For an adiabatic process,

dQ=0dQ = 0

Hence the molar heat capacity for process AA is

CA=0C_A = 0

Process BB has slope 4545^\circ or tan11\tan^{-1}1, so it is isothermal, using

PV=constantPV = \text{constant}

For an isothermal process, temperature does not change. Thus heat supplied is used in work done, and the effective molar heat capacity tends to

CB=C_B = \infty

Therefore, the correct statement is CA=0C_A = 0 and CB=C_B = \infty. The correct option is B.

Using process interpretation from the graph

Given: The graph distinguishes two processes AA and BB in a logP\log P vs. logV\log V plot. Find: which option matches their molar heat capacities.

The extracted solution states that process AA corresponds to an adiabatic path and process BB corresponds to an isothermal path.

For the adiabatic path,

dQ=0dQ = 0

By definition, the process heat capacity is zero, so

CA=0C_A = 0

For the isothermal path, the temperature remains constant. A finite amount of heat can be exchanged while

dT=0dT = 0

Therefore, from the process heat capacity idea, the ratio dQdT\frac{dQ}{dT} becomes unbounded, giving

CB=C_B = \infty

Hence the final answer remains CA=0C_A = 0 and CB=C_B = \infty, so the correct option is B.

Common mistakes

  • Mistake: treating process AA as isochoric merely from a visual guess about the graph. Why wrong: the solution identifies process AA from its slope as adiabatic, not constant volume. Do instead: use the slope information in the logP\log P vs. logV\log V plot and match it with PVγ=constantPV^{\gamma}=\text{constant}.

  • Mistake: assuming an isothermal process has zero heat capacity because temperature does not change. Why wrong: in an isothermal process, heat can still be supplied while dT=0dT=0, so the effective process heat capacity tends to infinity. Do instead: remember that for isothermal expansion of an ideal gas, heat goes into work, not temperature rise.

  • Mistake: confusing CAC_A and CBC_B with the state functions CPC_P and CVC_V directly. Why wrong: CAC_A and CBC_B are heat capacities for specific processes, which need not equal CPC_P or CVC_V. Do instead: first identify the nature of each process, then infer the corresponding process heat capacity.

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