Two thermodynamical processes are shown in the figure. The molar heat capacity for process and are and . The molar heat capacity at constant pressure and constant volume are represented by and respectively. Choose the correct statement:
- A
- B
- C
- D
Two thermodynamical processes are shown in the figure. The molar heat capacity for process and are and . The molar heat capacity at constant pressure and constant volume are represented by and respectively. Choose the correct statement:
Correct answer:B
Standard Method
Given: Two thermodynamical processes and are identified from a vs. figure. Find: the correct relation among , , and .
From the solution, process has slope where
so process is adiabatic, using
For an adiabatic process,
Hence the molar heat capacity for process is
Process has slope or , so it is isothermal, using
For an isothermal process, temperature does not change. Thus heat supplied is used in work done, and the effective molar heat capacity tends to
Therefore, the correct statement is and . The correct option is B.
Using process interpretation from the graph
Given: The graph distinguishes two processes and in a vs. plot. Find: which option matches their molar heat capacities.
The extracted solution states that process corresponds to an adiabatic path and process corresponds to an isothermal path.
For the adiabatic path,
By definition, the process heat capacity is zero, so
For the isothermal path, the temperature remains constant. A finite amount of heat can be exchanged while
Therefore, from the process heat capacity idea, the ratio becomes unbounded, giving
Hence the final answer remains and , so the correct option is B.
Mistake: treating process as isochoric merely from a visual guess about the graph. Why wrong: the solution identifies process from its slope as adiabatic, not constant volume. Do instead: use the slope information in the vs. plot and match it with .
Mistake: assuming an isothermal process has zero heat capacity because temperature does not change. Why wrong: in an isothermal process, heat can still be supplied while , so the effective process heat capacity tends to infinity. Do instead: remember that for isothermal expansion of an ideal gas, heat goes into work, not temperature rise.
Mistake: confusing and with the state functions and directly. Why wrong: and are heat capacities for specific processes, which need not equal or . Do instead: first identify the nature of each process, then infer the corresponding process heat capacity.
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