MCQMediumJEE 2024Isothermal & Adiabatic Processes

JEE Physics 2024 Question with Solution

During an adiabatic process, the pressure of a gas is proportional to the cube of its absolute temperature. The ratio of Cp/CvC_p/C_v is:

  • A

    53\frac{5}{3}

  • B

    32\frac{3}{2}

  • C

    75\frac{7}{5}

  • D

    97\frac{9}{7}

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: During an adiabatic process, PT3P \propto T^3.

Find: The ratio γ=CpCv\gamma = \frac{C_p}{C_v}.

For an adiabatic process, the relation between pressure and temperature is

PTγγ1=constantPT^{-\frac{\gamma}{\gamma-1}} = \text{constant}

Given PT3P \propto T^3, we write

P=kT3P = kT^3

So the temperature exponent must satisfy

3γγ1=03 - \frac{\gamma}{\gamma-1} = 0

Therefore,

3=γγ13 = \frac{\gamma}{\gamma-1} 3(γ1)=γ3(\gamma-1) = \gamma 3γ3=γ3\gamma - 3 = \gamma 2γ=32\gamma = 3 γ=32\gamma = \frac{3}{2}

Hence,

CpCv=32\frac{C_p}{C_v} = \frac{3}{2}

Therefore, the correct option is B.

Using adiabatic relation with ideal gas law

Given: PT3P \propto T^3, so

PT3=constantPT^{-3} = \text{constant}

Find: γ=CpCv\gamma = \frac{C_p}{C_v}.

From the adiabatic relation,

PVγ=constantPV^\gamma = \text{constant}

Using the ideal gas law,

V=nRTPV = \frac{nRT}{P}

Substitute into the adiabatic equation:

P(nRTP)γ=constantP\left(\frac{nRT}{P}\right)^\gamma = \text{constant}

Ignoring fixed constants,

P1γTγ=constantP^{1-\gamma}T^\gamma = \text{constant}

Since PT3P \propto T^3, compare powers of TT to obtain

γ1γ=3\frac{\gamma}{1-\gamma} = -3

So,

γ=3+3γ\gamma = -3 + 3\gamma 3=2γ3 = 2\gamma γ=32\gamma = \frac{3}{2}

Therefore, the ratio CpCv\frac{C_p}{C_v} is 32\frac{3}{2}, so the correct option is B.

Common mistakes

  • Using the adiabatic relation incorrectly as PV=constantPV=\text{constant}. That applies only to isothermal conditions for an ideal gas, not to an adiabatic process. Use PVγ=constantPV^\gamma=\text{constant} or the equivalent pressure-temperature form instead.

  • Equating the exponent of TT with the wrong sign. In the relation PTγγ1=constantPT^{-\frac{\gamma}{\gamma-1}}=\text{constant}, careful handling of the negative exponent is essential. Write the exponent equation explicitly before solving.

  • Confusing γ\gamma with Cv/CpC_v/C_p instead of Cp/CvC_p/C_v. The required ratio is γ=CpCv\gamma=\frac{C_p}{C_v}, so after solving for γ\gamma do not invert the answer.

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