MCQMediumJEE 2024Isothermal & Adiabatic Processes

JEE Physics 2024 Question with Solution

During an adiabatic process, the pressure of a gas is found to be proportional to the cube of its absolute temperature. The ratio of Cp/CvC_p/C_v for the gas is:

  • A

    53\frac{5}{3}

  • B

    32\frac{3}{2}

  • C

    75\frac{7}{5}

  • D

    97\frac{9}{7}

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: During an adiabatic process, PT3P \propto T^3.

Find: The ratio CpCv=γ\frac{C_p}{C_v} = \gamma.

For an adiabatic process, the pressure-temperature relation is

PTγγ1=constantPT^{-\frac{\gamma}{\gamma - 1}} = \text{constant}

Since PT3P \propto T^3, write

P=kT3P = kT^3

for some constant kk. Comparing powers of TT in the adiabatic relation:

3γγ1=03 - \frac{\gamma}{\gamma - 1} = 0

Now solve for γ\gamma:

3=γγ13 = \frac{\gamma}{\gamma - 1} 3(γ1)=γ3(\gamma - 1) = \gamma 3γ3=γ3\gamma - 3 = \gamma 2γ=32\gamma = 3 γ=32\gamma = \frac{3}{2}

Therefore, the ratio CpCv\frac{C_p}{C_v} is 32\frac{3}{2}. The correct option is B.

Using adiabatic relation with ideal gas law

Given: PT3P \propto T^3, so

PT3=constantPT^{-3} = \text{constant}

Find: γ=CpCv\gamma = \frac{C_p}{C_v}.

Start with the adiabatic relation:

PVγ=constantPV^\gamma = \text{constant}

Using the ideal gas law,

V=nRTPV = \frac{nRT}{P}

so

P(nRTP)γ=constantP\left(\frac{nRT}{P}\right)^\gamma = \text{constant}

Ignoring fixed constants nRnR, this becomes

P1γTγ=constantP^{1-\gamma}T^\gamma = \text{constant}

Using PT3P \propto T^3, equate exponents to obtain

γ1γ=3\frac{\gamma}{1-\gamma} = -3

Solving,

γ=3+3γ\gamma = -3 + 3\gamma 3=2γ3 = 2\gamma γ=32\gamma = \frac{3}{2}

Hence, the correct answer is 32\frac{3}{2}, that is, option B.

Common mistakes

  • Using the relation PVγ=constantPV^\gamma = \text{constant} directly without converting it into a pressure-temperature relation. This is wrong because the question gives a relation between PP and TT, not PP and VV. First express the adiabatic condition in terms of PP and TT.

  • Equating the proportionality PT3P \propto T^3 with P=T3P = T^3 and then forgetting that only exponents matter. The numerical constant does not affect the exponent comparison. Focus on matching the power of TT correctly.

  • Making an algebra mistake while solving 3=γγ13 = \frac{\gamma}{\gamma - 1}. This leads to a wrong value of γ\gamma. Cross-multiply carefully and simplify step by step to get 2γ=32\gamma = 3.

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