NVAEasyJEE 2023Bohr's Model & Hydrogen Spectrum

JEE Physics 2023 Question with Solution

The radius of the 2nd2^{\text{nd}} orbit of He+He^+ of Bohr's model is r1r_1 and that of the fourth orbit of Be3+Be^{3+} is represented as r2r_2. Now the ratio r2r1\frac{r_2}{r_1} is x:1x : 1. The value of xx _____

Answer

Correct answer:2

Step-by-step solution

Standard Method

Given: The radius of the 2nd2^{\text{nd}} orbit of He+He^+ is r1r_1 and the radius of the fourth orbit of Be3+Be^{3+} is r2r_2.

Find: The value of xx in r2r1=x\frac{r_2}{r_1} = x.

In Bohr's model, the radius of an orbit is proportional to

n2Z\frac{n^2}{Z}

where nn is the orbit number and ZZ is the atomic number.

So,

r2r1=(n2n1)2×Z1Z2\frac{r_2}{r_1} = \left( \frac{n_2}{n_1} \right)^2 \times \frac{Z_1}{Z_2}

Substituting the given values,

n1=2,n2=4,Z1=2,Z2=4n_1 = 2, \quad n_2 = 4, \quad Z_1 = 2, \quad Z_2 = 4

Therefore,

r2r1=(42)2×24\frac{r_2}{r_1} = \left( \frac{4}{2} \right)^2 \times \frac{2}{4} r2r1=22×12=4×12=2\frac{r_2}{r_1} = 2^2 \times \frac{1}{2} = 4 \times \frac{1}{2} = 2

Therefore, the value of xx is 22.

Direct Ratio Approach

Given: rn2Zr \propto \frac{n^2}{Z}.

Find: x=r2r1x = \frac{r_2}{r_1}.

Using proportionality directly,

r1222,r2424r_1 \propto \frac{2^2}{2}, \qquad r_2 \propto \frac{4^2}{4}

So,

r2r1=16442=42=2\frac{r_2}{r_1} = \frac{\frac{16}{4}}{\frac{4}{2}} = \frac{4}{2} = 2

This works because for hydrogen-like species in Bohr's model, orbit radius depends only on n2n^2 and inversely on ZZ.

Therefore, the value of xx is 22.

Common mistakes

  • Using radius proportional to nZ\frac{n}{Z} instead of n2Z\frac{n^2}{Z}. This gives an incorrect dependence on orbit number. Always use Bohr's radius relation with the square of nn.

  • Taking the atomic number of Be3+Be^{3+} as 33 because of the charge. This is wrong because ZZ is the number of protons, so for beryllium it is 44. Use charge only to identify that the species is hydrogen-like.

  • Reversing r2r1\frac{r_2}{r_1} as r1r2\frac{r_1}{r_2} during substitution. This changes the final numerical value. Write clearly which orbit corresponds to r1r_1 and which corresponds to r2r_2 before forming the ratio.

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