NVAEasyJEE 2023Bohr's Model & Hydrogen Spectrum

JEE Physics 2023 Question with Solution

If 917A˚917 \, \text{Å} be the lowest wavelength of Lyman series, then the lowest wavelength of Balmer series will be _____ A˚\text{Å}.

Answer

Correct answer:3668

Step-by-step solution

Standard Method

Given: The lowest wavelength of Lyman series is 917A˚917 \, \text{Å}.

Find: The lowest wavelength of Balmer series.

For the Lyman series, the lowest wavelength corresponds to the transition from n=n = \infty to n=1n = 1.

For the Balmer series, the lowest wavelength corresponds to the transition from n=n = \infty to n=2n = 2.

The energy E0E_0 for the Lyman series is related to the wavelength λ0\lambda_0 by:

E0=hcλ0E_0 = \frac{hc}{\lambda_0}

For Lyman, λ0=917A˚\lambda_0 = 917 \, \text{Å}, so:

E0=hc917A˚E_0 = \frac{hc}{917 \, \text{Å}}

For the Balmer series, the energy is related by:

E04=hcλ\frac{E_0}{4} = \frac{hc}{\lambda}

Substituting the energy of the Lyman series:

hc4×917A˚=hcλ\frac{hc}{4 \times 917 \, \text{Å}} = \frac{hc}{\lambda}

Thus, the wavelength for the Balmer series is:

λ=917×4=3668A˚\lambda = 917 \times 4 = 3668 \, \text{Å}

Therefore, the lowest wavelength of the Balmer series is 3668A˚3668 \, \text{Å}.

Series Limit Comparison

Given: The series-limit wavelength of Lyman series is 917A˚917 \, \text{Å}.

Find: The series-limit wavelength of Balmer series.

At the series limit, the emitted photon energy for transition to n=1n = 1 is proportional to 11, while for transition to n=2n = 2 it is proportional to 14\frac{1}{4}.

Hence, the Balmer-limit photon has one-fourth the energy of the Lyman-limit photon. Since

E=hcλE = \frac{hc}{\lambda}

wavelength is inversely proportional to energy.

So, if energy becomes one-fourth, wavelength becomes four times:

λBalmer=4λLyman\lambda_{\text{Balmer}} = 4\lambda_{\text{Lyman}}

Substitute the given value:

λBalmer=4×917=3668A˚\lambda_{\text{Balmer}} = 4 \times 917 = 3668 \, \text{Å}

Therefore, the required numerical value is 3668.

Common mistakes

  • Using the first visible Balmer line instead of the lowest wavelength Balmer limit is incorrect. The phrase lowest wavelength refers to the transition from n=n = \infty to the lower level, not from one finite level such as n=3n = 3. Use the series limit for both series.

  • Assuming wavelength is directly proportional to energy is wrong. From E=hcλE = \frac{hc}{\lambda}, wavelength is inversely proportional to energy. If the energy becomes one-fourth, the wavelength becomes four times larger.

  • Confusing the lower levels of the series leads to an incorrect ratio. Lyman series ends at n=1n = 1, whereas Balmer series ends at n=2n = 2. The energy of the limit state for Balmer is therefore reduced by a factor of 44 compared with Lyman.

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