NVAEasyJEE 2023Bohr's Model & Hydrogen Spectrum

JEE Physics 2023 Question with Solution

A light of energy 12.75eV12.75 \, \text{eV} is incident on a hydrogen atom in its ground state. The atom absorbs the radiation and reaches to one of its excited states. The angular momentum of the atom in the excited state is xπ×1017\frac{x}{\pi} \times 10^{-17} eVs. The value of xx is _____.

Answer

Correct answer:828

Step-by-step solution

Standard Method

Given: Energy of incident light is 12.75eV12.75 \, \text{eV}. The hydrogen atom is initially in the ground state.

Find: The value of xx in the angular momentum expression.

For hydrogen atom, energy in ground state is

E1=13.6eVE_1 = -13.6 \, \text{eV}

After absorbing the radiation,

13.6n2=13.6+12.75-\frac{13.6}{n^2} = -13.6 + 12.75

So,

13.6n2=0.85-\frac{13.6}{n^2} = -0.85

Hence,

n=16n = \sqrt{16} n=4n = 4

Now angular momentum in the excited state is

L=nh2π=4h2π=2hπL = \frac{nh}{2\pi} = \frac{4h}{2\pi} = \frac{2h}{\pi}

Using

h=4.14×1015eVsh = 4.14 \times 10^{-15} \, \text{eVs}

we get

L=2π×4.14×1015L = \frac{2}{\pi} \times 4.14 \times 10^{-15} L=828×1017πeVsL = \frac{828 \times 10^{-17}}{\pi} \, \text{eVs}

Therefore, the value of xx is 828828.

Common mistakes

  • Using the absorbed energy directly as the final state energy is incorrect. The atom starts from 13.6eV-13.6 \, \text{eV}, so the photon energy must be added to the initial energy level, not treated as the new level itself.

  • Forgetting that Bohr angular momentum is L=nh2πL = \frac{nh}{2\pi} is a common mistake. Using nhnh or h2π\frac{h}{2\pi} without the factor nn gives the wrong value.

  • Taking n=16n = 16 instead of n=4n = 4 is wrong. From n2=16n^2 = 16, the correct principal quantum number is n=4n = 4.

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