MCQMediumJEE Main 2023 · 30 January, Shift 2Ligands & Coordination Number

Chemistry Question from JEE Main 2023 · 30 January, Shift 2

**1L1 \, \text{L}, 0.02M0.02 \, \text{M} solution of [Co(NH3)5SO4]Br[Co(NH_3)_5SO_4]Br is mixed with 1L1 \, \text{L}, 0.02M0.02 \, \text{M} solution of [Co(NH3)5Br]SO4[Co(NH_3)_5Br]SO_4. The resulting solution is divided into two equal parts (X) and treated with excess AgNO3AgNO_3 solution and BaCl2BaCl_2 solution respectively as shown below:

1L1 \, \text{L} Solution (X) + AgNO3AgNO_3 solution (excess) Y\rightarrow Y

1L1 \, \text{L} Solution (X) + BaCl2BaCl_2 solution (excess) Z\rightarrow Z

The number of moles of Y and Z respectively are:**

  • A

    0.020.02, 0.020.02

  • B

    0.010.01, 0.010.01

  • C

    0.020.02, 0.010.01

  • D

    0.010.01, 0.020.02

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