NVAEasyJEE 2023Chromatography

JEE Chemistry 2023 Question with Solution

Following chromatogram was developed by adsorption of compound A on a 6cm6 \, \text{cm} TLC glass plate. The retardation factor of the compound A is _____ × 10110^{-1}.

Answer

Correct answer:0.6

Step-by-step solution

Standard Method

Given: A TLC glass plate of length 6cm6 \, \text{cm} is used for compound AA.

Find: The retardation factor RfR_f of compound AA.

The retardation factor is defined as

Rf=Distance traveled by the solute (A)Distance traveled by the solvent frontR_f = \frac{\text{Distance traveled by the solute (A)}}{\text{Distance traveled by the solvent front}}

From the solution, the solute travels 3.6cm3.6 \, \text{cm} and the solvent front travels 6cm6 \, \text{cm}.

Rf=3.66=0.6R_f = \frac{3.6}{6} = 0.6

Thus, the retardation factor of compound AA is 0.60.6.

The expression in the question corresponds to 6×1016 \times 10^{-1}, which is equal to 0.60.6.

Therefore, the final answer is 0.60.6.

Common mistakes

  • Using the total plate length directly as the answer is incorrect because RfR_f is a ratio of distances traveled. Always divide the solute distance by the solvent-front distance.

  • Writing 66 as the final numerical answer is incomplete here because the retardation factor itself is 0.60.6. The form 6×1016 \times 10^{-1} is equivalent, but the NVA answer should be entered as 0.60.6.

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