MCQEasyJEE 2025Chromatography

JEE Chemistry 2025 Question with Solution

Given below are two statements:

Statement (I): In partition chromatography, the stationary phase is a thin film of liquid present in the inert support.

Statement (II): In paper chromatography, the material of paper acts as a stationary phase.

In light of the above statements, choose the correct answer from the options given below:

  • A

    Both Statement I and Statement II are false

  • B

    Statement I is true but Statement II is false

  • C

    Both Statement I and Statement II are true

  • D

    Statement I is false but Statement II is true

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: Two statements about partition chromatography and paper chromatography.

Find: Which statement combination is correct.

In partition chromatography, the stationary phase is a thin liquid film supported on an inert material. Therefore, Statement (I) is true.

In paper chromatography, the stationary phase is not the paper material itself. It is the water held in the fibers of the paper, while the paper acts as a support. Therefore, Statement (II) is false.

Hence, the correct conclusion is: Statement I is true but Statement II is false.

The correct option is B.

Statement-wise Analysis

Given:

  • Statement (I): In partition chromatography, the stationary phase is a thin film of liquid present in the inert support.
  • Statement (II): In paper chromatography, the material of paper acts as a stationary phase.

Find: The correct option.

Step 1: Understand the basis of partition chromatography. In partition chromatography, separation occurs because components distribute themselves between two immiscible phases. The stationary phase is a thin film of liquid supported on an inert solid material.

So, Statement (I) is true.

Step 2: Understand the stationary phase in paper chromatography. In paper chromatography, the stationary phase is water adsorbed or trapped in the cellulose fibers of the paper. The paper itself serves only as a support.

So, Statement (II) is false.

Conclusion: Statement (I) is true but Statement (II) is false.

Therefore, the correct option is B.

Common mistakes

  • Assuming that the paper itself is the stationary phase in paper chromatography. This is incorrect because the actual stationary phase is the water retained in the paper fibers. Treat the paper only as the support.

  • Confusing adsorption chromatography with partition chromatography. In partition chromatography, separation depends on distribution between liquid phases, so the stationary phase is a liquid film, not a solid adsorbent surface.

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