NVAMediumJEE 2023Order & Molecularity

JEE Chemistry 2023 Question with Solution

For a certain chemical reaction XYX \rightarrow Y, the rate of formation of the product is plotted against time as shown in the figure. The number of correct statements from the following is _____.

Answer: 22

Statements: (A) Overall order of this reaction is one. (B) Order of this reaction cannot be determined. (C) In region-II and IIIIII, the reaction is of first and zero order respectively. (D) In region-IIII, the reaction is of first order.

Find the number of correct statement(s).

Answer

Correct answer:2

Step-by-step solution

Standard Method

Given: A graph-based question about reaction order in regions II, IIII and IIIIII.

Find: The number of correct statements among the listed options.

The solution states:

  • Region-II shows linear behavior, so it is first order.
  • Region-IIII shows non-linear behavior, so it is not first order.
  • Region-IIIIII shows constant rate, so it is zero order.

Thus:

  • (A) is incorrect.
  • (B) is incorrect.
  • (C) is correct.
  • (D) is incorrect.

The solution also introduces an extra statement (E) saying the order in region-IIII lies between 0.10.1 and 0.90.9, and concludes that the correct statements are (C) and (E), giving the number of correct statements as 22.

However, option (E) is not present in the listed options list. Therefore, the provided solution and the visible options are inconsistent.

From the visible options alone, only (C) is correct. But since the source solution concludes the final answer is 22, the answer cannot be mapped unambiguously to the listed options.

Therefore, the extracted answer is marked AMBIGUOUS due to mismatch between the solution and the listed options.

Statement Check

Given: Region-wise behavior is described in the solution.

Find: Which listed statements are correct.

  1. In region-II, the rate varies linearly, so this is first-order behavior.
  2. In region-IIIIII, the rate becomes constant, so this is zero-order behavior.
  3. In region-IIII, the behavior is non-linear, so it is not first order.

Checking the listed statements:

  • (A) Overall order is one — false.
  • (B) Order cannot be determined — false, because region-wise order is inferred.
  • (C) Region-II first order and region-IIIIII zero order — true.
  • (D) Region-IIII first order — false.

So among the listed options, the count is 11. But the solution says the count is 22 by using an additional statement (E) not present in the options. This mismatch prevents a clean MCQ answer label.

Common mistakes

  • Assuming the overall reaction order must be the same in all regions is incorrect. The graph-based explanation explicitly treats the regions separately, so order changes with region-wise behavior.

  • Interpreting any curved or non-linear part as first order is wrong. First-order behavior is identified from a linear dependence, whereas non-linear behavior indicates some other order.

  • Ignoring the mismatch between the listed options and the solution can lead to a wrong final count. Always verify that every statement referenced in the solution actually appears in the options.

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