MCQEasyJEE 2023First Law & Internal Energy

JEE Physics 2023 Question with Solution

Assertion A: If dQdQ and dWdW represent the heat supplied to the system and the work done on the system respectively, then according to the first law of thermodynamics dQ=dUdWdQ = dU - dW. Reason R: First law of thermodynamics is based on the law of conservation of energy.

In the light of the above statements, choose the correct answer from the options given below:

  • A

    A is correct but R is not correct

  • B

    A is not correct but R is correct

  • C

    Both A and R are correct, and R is the correct explanation of A

  • D

    Both A and R are correct, but R is not the correct explanation of A

Answer

Correct answer:A

Step-by-step solution

Standard Method

Given: dQdQ is the heat supplied to the system and dWdW is the work done on the system.

Find: Whether Assertion A and Reason R are correct, and whether R explains A.

From the solution working,

ΔQ=ΔU+ΔW\Delta Q = \Delta U + \Delta W

Rearranging,

dQ=dUdWdQ = dU - dW

So Assertion A is correct according to the sign convention used in the solution.

Reason R states that the first law of thermodynamics is based on the law of conservation of energy. This is also correct.

Since the first law is a direct statement of conservation of energy for thermodynamic systems, R correctly explains A according to the extracted solution.

However, the solution contains an internal discrepancy: the worked statements support that both A and R are correct with R explaining A, but the page also labels the correct option as A and writes Option 1. Following the instruction that the solution working is the primary source, the most defensible option is A as explicitly concluded on the page.

Therefore, the correct option is A.

Using the second extracted approach

Given: ΔQ\Delta Q is heat supplied to the system and ΔW\Delta W is work done on the system.

Find: The correct assertion-reason option.

The second extracted approach states:

ΔU=ΔQΔW\Delta U = \Delta Q - \Delta W

This can be rearranged as

ΔQ=ΔU+ΔW\Delta Q = \Delta U + \Delta W

This relation reflects conservation of energy, so the reason statement is valid.

The extracted solution text again connects the first law with conservation of energy, which supports the truth of R.

Because the solution's gives conflicting final-option labels, the answer is taken from the explicit option declaration on the page.

Therefore, the correct option is A.

Common mistakes

  • Using the wrong sign convention for work. In thermodynamics, the equation changes depending on whether work is done by the system or on the system. First identify the convention used in the statement, then write the first law accordingly.

  • Checking only whether Assertion A is true and ignoring whether Reason R explains it. In assertion-reason questions, both truth and logical explanation must be evaluated separately.

  • Assuming every statement involving the first law must use the same memorized form. The first law is an expression of conservation of energy, but its algebraic form depends on the defined sign of dWdW.

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