MCQEasyJEE 2023Electron Gain Enthalpy & Electronegativity

JEE Chemistry 2023 Question with Solution

Which of the following represents the correct order of metallic character of the given elements?

  • A

    Si<Be<Mg<KSi < Be < Mg < K

  • B

    Be<Si<Mg<KBe < Si < Mg < K

  • C

    K<Mg<Be<SiK < Mg < Be < Si

  • D

    Be<Si<K<MgBe < Si < K < Mg

Answer

Correct answer:A

Step-by-step solution

Standard Method

Given: The order of metallic character is to be compared for SiSi, BeBe, MgMg, and KK.

Find: The correct increasing order of metallic character.

Metallic character refers to the ability of an element to lose electrons and form positive ions. As we move down a group in the periodic table, the atomic size increases, and the outer electrons are farther from the nucleus, making it easier for the element to lose electrons. Therefore, metallic character increases down a group.

As we move from left to right across a period, the atomic size decreases and the effective nuclear charge increases, making it harder for an element to lose electrons. Therefore, metallic character decreases across a period from left to right.

Among the given elements, KK is an alkali metal in Group 11, so it has the highest metallic character. SiSi is a metalloid in Group 1414, so it has the least metallic character among the given elements. Between BeBe and MgMg, metallic character increases down the group, so Mg>BeMg > Be.

Hence, the correct order is

Si<Be<Mg<KSi < Be < Mg < K

Therefore, the correct option is A.

The solution displays D as the correct option label, but its written sequence concludes Si<Be<Mg<KSi < Be < Mg < K, which matches option A. Therefore, the sequence in the explanation is taken as authoritative.

Trend-Based Explanation

Given: Metallic character depends on the tendency to lose electrons.

Find: Which arrangement shows increasing metallic character.

Use periodic trends:

  1. Down a group, metallic character increases.
  2. Across a period from left to right, metallic character decreases.

Applying this:

  • KK is most metallic.
  • SiSi is least metallic.
  • Between BeBe and MgMg, MgMg is more metallic because it lies below BeBe in the same group.

So the increasing order becomes

Si<Be<Mg<KSi < Be < Mg < K

Thus, the correct option is A.

Common mistakes

  • Assuming metallic character increases from left to right across a period is incorrect because effective nuclear charge increases and electrons are held more strongly. Use the rule that metallic character decreases from left to right.

  • Comparing BeBe and MgMg incorrectly can lead to a wrong order. Since both are in the same group, metallic character increases downward, so MgMg is more metallic than BeBe.

  • Relying only on the option label shown in the solution can be misleading here because the label conflicts with the written explanation. Always verify which option actually matches the derived sequence.

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