MCQEasyJEE 2023Isothermal & Adiabatic Processes

JEE Physics 2023 Question with Solution

Match List I with List II:

A matching table with List I containing Isothermal, Adiabatic, Isochoric and Isobaric processes, and List II containing statements about internal energy and work done by the gas.

Choose the correct answer from the options given below :

  • A

    A-II, B-I, C-III, D-IV

  • B

    A-II, B-I, C-IV, D-III

  • C

    A-I, B-II, C-IV, D-III

  • D

    A-I, B-II, C-III, D-IV

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: Match thermodynamic processes in List I with the correct statements in List II.

Find: The correct correspondence between A, B, C, D and I, II, III, IV.

For an ideal gas,

ΔU=nCvΔT\Delta U = nC_v \Delta T

So internal energy depends only on temperature change.

For isothermal process, temperature remains constant, so

ΔT=0\Delta T = 0

Hence,

ΔU=0\Delta U = 0

Therefore, A (\to) II.

For adiabatic process,

ΔQ=0\Delta Q = 0

Using the first law of thermodynamics,

ΔQ=ΔU+ΔW\Delta Q = \Delta U + \Delta W

So,

ΔU=ΔW\Delta U = -\Delta W

If work is done by the gas, ΔW>0\Delta W > 0, hence ΔU<0\Delta U < 0. Therefore, work done by the gas decreases internal energy. So B (\to) I.

For isochoric process, volume remains constant, hence no work is done:

ΔW=0\Delta W = 0

Therefore, C (\to) IV.

For isobaric process,

ΔW=PΔV0\Delta W = P\Delta V \neq 0

Also,

ΔU=nCvΔT0\Delta U = nC_v \Delta T \neq 0

So the heat absorbed is used partly to increase internal energy and partly to do work. Therefore, D (\to) III.

Thus the correct matching is A-II, B-I, C-IV, D-III.

The correct option is B.

Process-wise Interpretation

Given: Four thermodynamic processes and four statements.

Find: The correct one-to-one matching.

  1. Isothermal process: temperature is constant, so internal energy of an ideal gas does not change.
  2. Adiabatic process: no heat exchange occurs. If the gas does work, that energy comes from its internal energy, so internal energy decreases.
  3. Isochoric process: volume is constant, therefore
ΔW=0\Delta W = 0
  1. Isobaric process: pressure is constant, and generally both temperature and volume change. Hence supplied heat is split between increasing internal energy and doing work.

This gives:

  • A-II
  • B-I
  • C-IV
  • D-III

So the correct option is B.

Common mistakes

  • Confusing isothermal with adiabatic. In an isothermal process, temperature remains constant, so for an ideal gas ΔU=0\Delta U = 0. Do not assume ΔQ=0\Delta Q = 0 there; that condition belongs to the adiabatic process.

  • Assuming adiabatic means internal energy does not change. That is incorrect because ΔQ=0\Delta Q = 0 only means no heat exchange. Use the first law to get ΔU=ΔW\Delta U = -\Delta W when work is done by the gas.

  • Forgetting that in an isochoric process volume is constant. Since ΔV=0\Delta V = 0, no boundary work is done. Do not match isochoric with partial work done; match it with zero work.

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