Given: Statements about hydrogen atom spectrum and Rydberg's constant R.
Find: Which statements among A, B, C, D are correct.
Use the Rydberg formula:
λ1=R(n121−n221)
Maximum wavelength corresponds to the smallest energy gap, so for a given series take n2=n1+1. Minimum wavelength corresponds to the series limit, so take n2=∞.
For Statement A: Lyman series has n1=1. For maximum wavelength, take n2=2.
λ1=R(1−41)=43R
Hence,
λ=3R4
So A is correct.
For Statement B: Balmer series corresponds to n1=2 and it lies in the visible region of the spectrum. So B is correct.
For Statement C: Paschen series has n1=3. For minimum wavelength, take n2=∞.
λ1=R(91−0)=9R
Hence,
λ=R9
So C is correct.
For Statement D: Lyman series minimum wavelength occurs at n2=∞.
λ1=R(1−0)=R
Hence,
λ=R1
This is not 4R5, so D is incorrect.
Therefore, the correct statements are A, B and C only. The correct option is A.