MCQEasyJEE 2026Molecular Speeds (rms, Average, Most Probable)

JEE Physics 2026 Question with Solution

The r.m.s. speed of oxygen molecules at 47C47^\circ \text{C} is equal to that of the hydrogen molecules kept at _____ C^\circ \text{C}. (Mass of oxygen molecule/mass of hydrogen molecule = 32/232/2)

  • A

    20-20

  • B

    253-253

  • C

    235-235

  • D

    100-100

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: Oxygen molecules are at 47C47^\circ \text{C} and their r.m.s. speed is equal to that of hydrogen molecules. Mass ratio is 322\frac{32}{2}.

Find: The temperature of hydrogen molecules in C^\circ \text{C}.

For r.m.s. speed,

vrms=3RTMv_{\text{rms}} = \sqrt{\frac{3RT}{M}}

If the speeds are equal, then

T1M1=T2M2\frac{T_1}{M_1} = \frac{T_2}{M_2}

Convert oxygen temperature to Kelvin:

TO=273+47=320KT_O = 273 + 47 = 320 \, \text{K}

For oxygen, MO=32M_O = 32 and for hydrogen, MH=2M_H = 2. So,

32032=TH2\frac{320}{32} = \frac{T_H}{2} 10=TH210 = \frac{T_H}{2} TH=20KT_H = 20 \, \text{K}

Now convert back to Celsius:

tH=TH273=20273=253Ct_H = T_H - 273 = 20 - 273 = -253^\circ \text{C}

Therefore, the hydrogen molecules are kept at 253C-253^\circ \text{C}. The correct option is B.

Common mistakes

  • Using Celsius directly in the ratio of temperatures is incorrect because the r.m.s. speed formula requires absolute temperature. Convert 47C47^\circ \text{C} to 320K320 \, \text{K} before applying the relation.

  • Using the mass ratio in the wrong order gives the wrong temperature. Since TM\frac{T}{M} is constant for equal r.m.s. speeds, use 32032=TH2\frac{320}{32} = \frac{T_H}{2}, not the inverse.

  • Forgetting to convert the final Kelvin temperature back to Celsius leads to reporting 20K20 \, \text{K} as the answer. The question asks for C^\circ \text{C}, so compute 20273=253C20 - 273 = -253^\circ \text{C}.

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