MCQMediumJEE 2025Surface Tension & Capillarity

JEE Physics 2025 Question with Solution

Two water drops each of radius rr coalesce to form a bigger drop. If TT is the surface tension, the surface energy released in this process is:

  • A

    4πr2T[222/3]4\pi r^2 T \left[ 2 - 2^{2/3} \right]

  • B

    4πr2T[2123]4\pi r^2 T \left[ 2^{-1} - 2^3 \right]

  • C

    4πr2T[1+2]4\pi r^2 T \left[ 1 + \sqrt{2} \right]

  • D

    4πr2T[21]4\pi r^2 T \left[ \sqrt{2} - 1 \right]

Answer

Correct answer:A

Step-by-step solution

Standard Method

Given: Two identical water drops each have radius rr and surface tension TT.

Find: The surface energy released when they coalesce into one bigger drop.

The surface energy of a liquid drop is proportional to its surface area:

E=4πR2TE = 4\pi R^2 T

When two drops merge, volume is conserved.

Using volume conservation:

2×43πr3=43πR32 \times \frac{4}{3}\pi r^3 = \frac{4}{3}\pi R^3

So,

R3=2r3R^3 = 2r^3

and hence,

R=21/3rR = 2^{1/3}r

Energy Change Calculation

Initial total surface energy of the two smaller drops is:

Ei=2×4πr2T=8πr2TE_i = 2 \times 4\pi r^2 T = 8\pi r^2 T

Final surface energy of the larger drop is:

Ef=4πR2T=4π(21/3r)2T=4π22/3r2TE_f = 4\pi R^2 T = 4\pi (2^{1/3}r)^2 T = 4\pi 2^{2/3} r^2 T

Final Difference

Energy released equals the decrease in surface energy:

ΔE=EiEf\Delta E = E_i - E_f

Therefore,

ΔE=8πr2T4π22/3r2T=4πr2T(222/3)\Delta E = 8\pi r^2 T - 4\pi 2^{2/3} r^2 T = 4\pi r^2 T (2 - 2^{2/3})

Therefore, the surface energy released is 4πr2T(222/3)4\pi r^2 T (2 - 2^{2/3}) and the correct option is A.

Common mistakes

  • Using surface area conservation instead of volume conservation is incorrect because drops merge without loss of liquid volume. First conserve volume to find the new radius, then compute the change in surface area.

  • Adding radii directly to get the new radius is wrong because radius does not add linearly during coalescence. The correct relation comes from R3=2r3R^3 = 2r^3.

  • Taking energy released as EfEiE_f - E_i gives the wrong sign. Since surface area decreases after coalescence, released energy is EiEfE_i - E_f.

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