MCQMediumJEE Main 2025 · 2 April, Shift 1Salt Analysis (Cations & Anions)

Chemistry Question from JEE Main 2025 · 2 April, Shift 1

Choose the correct tests with respective observations.

(A) CuSO4\mathrm{CuSO_4} (acidified with acetic acid) + K4[Fe(CN)6]+\ \mathrm{K_4[Fe(CN)_6]} \rightarrow Chocolate brown precipitate.

(B) FeCl3+ K4[Fe(CN)6]\mathrm{FeCl_3} +\ \mathrm{K_4[Fe(CN)_6]} \rightarrow Prussian blue precipitate.

(C) ZnCl2+ K4[Fe(CN)6]\mathrm{ZnCl_2} +\ \mathrm{K_4[Fe(CN)_6]}, neutralised with NH4OH\mathrm{NH_4OH} \rightarrow White or bluish white precipitate.

(D) MgCl2+ K4[Fe(CN)6]\mathrm{MgCl_2} +\ \mathrm{K_4[Fe(CN)_6]} \rightarrow Blue precipitate.

(E) BaCl2+ K4[Fe(CN)6]\mathrm{BaCl_2} +\ \mathrm{K_4[Fe(CN)_6]}, neutralised with NaOH\mathrm{NaOH} \rightarrow White precipitate.

Choose the correct answer from the options given below:

  • A

    (A), (B) and (C) only

  • B

    (B), (D) and (E) only

  • C

    (C), (D) and (E) only

  • D

    (A), (D) and (E) only

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