The sum of sigma () and pi () bonds in Hex-1,3-dien-5-yne is:
JEE Chemistry 2025 Question with Solution
Answer
Correct answer:17
Step-by-step solution
Standard Method
Given: We need the sum of sigma () and pi () bonds in Hex-1,3-dien-5-yne.
Find: Total number of bonds present as the sum of sigma and pi bonds.
The solution gives the structure as
Each double bond has sigma bond and pi bond, while each triple bond has sigma bond and pi bonds.
Counting all bonds in the given structure gives a total of bonds.
Therefore, the sum of sigma and pi bonds is .
Bond-Type Counting Idea
Given: Count sigma and pi bonds separately for the given compound.
Find: The total bond count.
Use the bond-type rule:
- Single bond only
- Double bond
- Triple bond
The provided solution identifies the final total directly from the displayed structure and states that the total number of sigma and pi bonds is .
Therefore, the required numerical value is .
Common mistakes
Counting a double bond as two sigma bonds is incorrect because a double bond contains one sigma bond and one pi bond. Always split multiple bonds into their sigma and pi components before adding.
Counting a triple bond as three sigma bonds is wrong because a triple bond contains one sigma bond and two pi bonds. Treat bond multiplicity carefully instead of equating it directly with sigma bonds.
Ignoring bonds to hydrogen leads to an undercount because bonds are also sigma bonds. Include all single bonds attached to hydrogen in the total.
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