MCQEasyJEE 2025Concentration Terms (Molarity, Molality, etc.)

JEE Chemistry 2025 Question with Solution

Assume a living cell with 0.9%0.9\% (w/ww/w) of glucose solution (aqueous). This cell is immersed in another solution having equal mole fraction of glucose and water. (Consider the data up to first decimal place only) The cell will:

  • A

    Shrink since solution is 0.5%0.5\% (w/ww/w)

  • B

    Shrink since solution is 0.45%0.45\% (w/ww/w) as a result of association of glucose molecules (due to hydrogen bonding)

  • C

    Show no change in volume since solution is 0.9%0.9\% (w/ww/w)

  • D

    Swell up since solution is 1%1\% (w/ww/w)

Answer

Correct answer:C

Step-by-step solution

Standard Method

Given: The cell contains 0.9%0.9\% (w/ww/w) glucose solution. The surrounding solution has the same mole fraction of glucose as the cell solution.

Find: Whether the cell shrinks, swells, or shows no change in volume.

For osmosis, compare the effective solute concentration on both sides of the membrane. If both sides have the same concentration, osmotic pressure is the same and there is no net flow of water.

From the extracted solution:

nglucose=0.9180=0.005n_{\text{glucose}} = \frac{0.9}{180} = 0.005 nwater=99.118=5.5n_{\text{water}} = \frac{99.1}{18} = 5.5 xglucose=0.0050.005+5.50.0009x_{\text{glucose}} = \frac{0.005}{0.005 + 5.5} \approx 0.0009

Since the external solution is stated to have the same mole fraction as the cell solution, both solutions are isotonic.

Therefore, there is no net movement of water across the membrane, so the cell shows no change in volume.

The correct option is C.

Using Osmosis Concept

Given: In osmosis, water moves from lower solute concentration to higher solute concentration. The cell has glucose solution of 0.9%0.9\% (w/ww/w), and the outside solution is described as having equal mole fraction corresponding to the same concentration condition in the problem.

Find: The effect on the cell volume.

The hint states that if concentrations are equal, there is no net movement of water. The solution explicitly concludes that the internal and external solutions have the same osmotic concentration.

Hence, the cell is in an isotonic medium.

Therefore, the cell will show no change in volume since solution is 0.9%0.9\% (w/ww/w).

The correct option is C.

Common mistakes

  • Comparing w/w%w/w\% directly without using the problem's stated equality of mole fraction. Osmosis depends on relative solute concentration across the membrane, so the key comparison is isotonicity, not a casual percentage comparison. Use the condition given in the question first.

  • Assuming that equal mole fraction of glucose and water outside means the cell must shrink immediately. That interpretation ignores the solution's intended comparison and final isotonic conclusion. Follow the stated osmotic argument used in the provided solution.

  • Thinking that any presence of glucose association by hydrogen bonding changes the answer here. The provided solution does not use association to determine osmotic behavior. Use the concentration comparison actually established in the solution.

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