NVAMediumJEE 2025Stoichiometry & Calculations

JEE Chemistry 2025 Question with Solution

Consider the following reaction occurring in the blast furnace. Fe3O4(s)+4CO(g)3Fe(l)+4CO2(g)Fe_3O_4(s) + 4CO(g) \rightarrow 3Fe(l) + 4CO_2(g) ‘x’ kg of iron is produced when 2.32×1032.32 \times 10^3 kg Fe3O4Fe_3O_4 and 2.8×1022.8 \times 10^2 kg CO are brought together in the furnace. The value of ‘x’ is _____ (nearest integer).

Answer

Correct answer:420

Step-by-step solution

Stoichiometric calculation using limiting reactant

Given:

  • Reaction: Fe3O4(s)+4CO(g)3Fe(l)+4CO2(g)Fe_3O_4(s) + 4CO(g) \rightarrow 3Fe(l) + 4CO_2(g)
  • Mass of Fe3O4=2.32×103kg=2.32×106gFe_3O_4 = 2.32 \times 10^3 \, \text{kg} = 2.32 \times 10^6 \, \text{g}
  • Mass of CO=2.8×102kg=2.8×105gCO = 2.8 \times 10^2 \, \text{kg} = 2.8 \times 10^5 \, \text{g}

Find: Mass of iron produced, xx.

First convert the given masses to moles.

Moles of Fe3O4=2.32×106g232g/mol=104mol\text{Moles of } Fe_3O_4 = \frac{2.32 \times 10^6 \, \text{g}}{232 \, \text{g/mol}} = 10^4 \, \text{mol} Moles of CO=2.8×105g28g/mol=104mol\text{Moles of } CO = \frac{2.8 \times 10^5 \, \text{g}}{28 \, \text{g/mol}} = 10^4 \, \text{mol}

From the balanced equation, 11 mole of Fe3O4Fe_3O_4 reacts with 44 moles of COCO. Thus, for 10410^4 moles of Fe3O4Fe_3O_4, the required moles of COCO are:

104×4=4×104 mol10^4 \times 4 = 4 \times 10^4 \text{ mol}

But only 10410^4 moles of COCO are available, so CO is the limiting reactant and Fe3O4Fe_3O_4 is in excess.

Now use the stoichiometric ratio between COCO and FeFe.

4 mol of CO3 mol of Fe4 \text{ mol of } CO \rightarrow 3 \text{ mol of } Fe

Therefore,

Moles of Fe=34×104=7.5×103mol\text{Moles of } Fe = \frac{3}{4} \times 10^4 = 7.5 \times 10^3 \, \text{mol}

Convert moles of iron to mass.

Mass of Fe=7.5×103mol×56g/mol=420×103g=420kg\text{Mass of } Fe = 7.5 \times 10^3 \, \text{mol} \times 56 \, \text{g/mol} = 420 \times 10^3 \, \text{g} = 420 \, \text{kg}

Therefore, the value of xx is 420420.

Expanded molar-mass method

Given: Fe3O4(s)+4CO(g)3Fe(l)+4CO2(g)Fe_3O_4(s) + 4CO(g) \rightarrow 3Fe(l) + 4CO_2(g)

Find: The mass of iron formed.

Calculate molar masses:

Molar mass of Fe3O4=3×56+4×16=232g/mol\text{Molar mass of } Fe_3O_4 = 3 \times 56 + 4 \times 16 = 232 \, \text{g/mol} Molar mass of CO=12+16=28g/mol\text{Molar mass of } CO = 12 + 16 = 28 \, \text{g/mol} Molar mass of Fe=56g/mol\text{Molar mass of } Fe = 56 \, \text{g/mol}

Now find the available moles:

Moles of Fe3O4=2.32×106232=10000\text{Moles of } Fe_3O_4 = \frac{2.32 \times 10^6}{232} = 10000 Moles of CO=2.8×10528=10000\text{Moles of } CO = \frac{2.8 \times 10^5}{28} = 10000

Check the limiting reagent using the stoichiometric ratio Fe3O4:CO=1:4Fe_3O_4 : CO = 1:4. For 1000010000 moles of Fe3O4Fe_3O_4, the required COCO is:

10000×4=40000 mol10000 \times 4 = 40000 \text{ mol}

Since only 1000010000 moles of COCO are present, COCO is the limiting reagent.

From the balanced equation:

4 mol CO3 mol Fe4 \text{ mol } CO \rightarrow 3 \text{ mol } Fe

So,

Moles of Fe=34×10000=7500\text{Moles of } Fe = \frac{3}{4} \times 10000 = 7500 Mass of Fe=7500×56=420000g=420kg\text{Mass of } Fe = 7500 \times 56 = 420000 \, \text{g} = 420 \, \text{kg}

Hence, the required numerical answer is 420420.

Common mistakes

  • A common mistake is treating Fe3O4Fe_3O_4 and COCO as if they react in a 1:11:1 mole ratio. This is incorrect because the balanced equation requires 1:41:4. Always use the stoichiometric coefficients from the balanced reaction before identifying the limiting reactant.

  • Another mistake is comparing masses directly instead of converting them to moles. Stoichiometric relations apply to moles, not kilograms or grams. First convert each given mass using its molar mass, then compare the reacting amounts.

  • Students may copy the answer key and report 420g420 \, \text{g}. This is wrong because the worked solution clearly gives 420000g=420kg420000 \, \text{g} = 420 \, \text{kg}. The numerical value asked for in kilograms is therefore 420420.

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