MCQMediumJEE 2025Diazonium Salts & Reactions

JEE Chemistry 2025 Question with Solution

Consider the following sequence of reactions :

Reaction sequence showing nitrobenzene treated with Sn + HCl, then NaNO2 and HCl at 0 degree Celsius, followed by Cu2Cl2 and Na in ether to form product A.

Molar mass of the product formed (A) is _____ g mol1^{-1}.

  • A

    154154

  • B

    144144

  • C

    130130

  • D

    160160

Answer

Correct answer:A

Step-by-step solution

Standard Method

Given: A reaction sequence is shown, and the molar mass of product A is to be found.

Find: The molar mass of product A in g mol1^{-1}.

From the solution, the final product A has molecular formula C8H10O3\mathrm{C_8H_{10}O_3}.

Using atomic masses:

C=12.011g mol1H=1.008g mol1O=16.00g mol1\begin{aligned} \text{C} &= 12.011 \, \text{g mol}^{-1} \\ \text{H} &= 1.008 \, \text{g mol}^{-1} \\ \text{O} &= 16.00 \, \text{g mol}^{-1} \end{aligned}

Now compute the molar mass contribution of each element:

Mass from C=8×12.011=96.088g mol1Mass from H=10×1.008=10.080g mol1Mass from O=3×16.00=48.000g mol1\begin{aligned} \text{Mass from C} &= 8 \times 12.011 = 96.088 \, \text{g mol}^{-1} \\ \text{Mass from H} &= 10 \times 1.008 = 10.080 \, \text{g mol}^{-1} \\ \text{Mass from O} &= 3 \times 16.00 = 48.000 \, \text{g mol}^{-1} \end{aligned}

Adding these:

M=96.088+10.080+48.000=154.168g mol1M = 96.088 + 10.080 + 48.000 = 154.168 \, \text{g mol}^{-1}

Rounding to the nearest whole number, the molar mass is 154g mol1154 \, \text{g mol}^{-1}. Therefore, the correct option is A.

Using the extracted final formula

Given: The reaction sequence leads to product A.

Find: Its molar mass.

The available solution states that after identifying the final structure from the figure, product A is assigned the formula C8H10O3\mathrm{C_8H_{10}O_3}.

The molar mass is obtained by summing atomic masses according to the subscripts:

M=8(MC)+10(MH)+3(MO)M = 8(M_{\mathrm{C}}) + 10(M_{\mathrm{H}}) + 3(M_{\mathrm{O}})

Substitute standard atomic masses:

M=8(12.011)+10(1.008)+3(16.00)M = 8(12.011) + 10(1.008) + 3(16.00) M=96.088+10.080+48.000M = 96.088 + 10.080 + 48.000 M=154.168g mol1M = 154.168 \, \text{g mol}^{-1}

Thus, the molar mass of the product formed is 154g mol1154 \, \text{g mol}^{-1}, so the correct option is A.

Common mistakes

  • A common mistake is to infer the product mass directly from one reagent in the sequence. This is wrong because the molar mass must be calculated from the final product formula, not from an intermediate or starting compound. First identify A, then add atomic masses.

  • Students may use incorrect atomic masses such as taking C = 13 or H = 1 too early without checking the required precision. This can shift the total. Use consistent atomic masses first, then round only at the end.

  • Another mistake is adding the subscripts incorrectly in C8H10O3\mathrm{C_8H_{10}O_3}, especially missing one oxygen or counting hydrogen wrongly. This gives a wrong total molar mass. Write each elemental contribution separately before summing.

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