MCQEasyJEE 2025Bohr Model & Hydrogen Spectrum

JEE Chemistry 2025 Question with Solution

Radius of the first excited state of Helium ion is given as: a0a_0 = radius of first stationary state of hydrogen atom.

  • A

    r=a02r = \frac{a_0}{2}

  • B

    r=a04r = \frac{a_0}{4}

  • C

    r=4a0r = 4a_0

  • D

    r=2a0r = 2a_0

Answer

Correct answer:D

Step-by-step solution

Standard Method

Given: Helium ion is He+He^+ and the question asks for the radius of the first excited state. Also, a0a_0 is the radius of the first stationary state of the hydrogen atom.

Find: Radius of the first excited state of He+He^+.

For a hydrogen-like ion, the radius of the **nn**th orbit is

rn=a0n2Zr_n = a_0 \frac{n^2}{Z}

where nn is the principal quantum number and ZZ is the atomic number.

For the helium ion He+He^+, we have Z=2Z = 2. The first excited state means n=2n = 2.

Substituting these values,

r2=a0222=a042=2a0r_2 = a_0 \frac{2^2}{2} = a_0 \frac{4}{2} = 2a_0

Therefore, the radius of the first excited state of helium ion is 2a02a_0. The correct option is D.

Common mistakes

  • Using n=1n = 1 instead of n=2n = 2. This is wrong because the first excited state corresponds to n=2n = 2, not the ground state. Always identify the correct energy level before substitution.

  • Forgetting that He+He^+ is a hydrogen-like ion with Z=2Z = 2. This gives an incorrect radius because the nuclear charge must appear in the denominator. Always use the atomic number of the ion.

  • Using the formula without the ZZ factor, as if the species were hydrogen. That is incorrect because helium ion has a stronger nuclear attraction than hydrogen. Use rn=n2a0Zr_n = \frac{n^2 a_0}{Z} for hydrogen-like ions.

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