MCQEasyJEE 2025Photoelectric Effect

JEE Physics 2025 Question with Solution

The work functions of cesium (Cs) and lithium (Li) metals are 1.9eV1.9 \, \text{eV} and 2.5eV2.5 \, \text{eV}, respectively. If we incident a light of wavelength 550nm550 \, \text{nm} on these two metal surfaces, then photo-electric effect is possible for the case of:

  • A

    Li only

  • B

    Cs only

  • C

    Neither Cs nor Li

  • D

    Both Cs and Li

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: Work function of Cs is 1.9eV1.9 \, \text{eV}, work function of Li is 2.5eV2.5 \, \text{eV}, and incident wavelength is 550nm550 \, \text{nm}.

Find: For which metal the photoelectric effect is possible.

For photoelectric emission to occur, the incident photon energy must be greater than the work function.

The energy of the incident photon is

E=1240λ=12405502.25eVE = \frac{1240}{\lambda} = \frac{1240}{550} \approx 2.25 \, \text{eV}

Now compare this with the work functions:

For Cs,

2.25eV>1.9eV2.25 \, \text{eV} > 1.9 \, \text{eV}

So, photoelectric effect is possible for Cs.

For Li,

2.25eV<2.5eV2.25 \, \text{eV} < 2.5 \, \text{eV}

So, photoelectric effect is not possible for Li.

Therefore, the correct option is B.

Energy Comparison Using $$E = \frac{hc}{\lambda}$$

Given:

  • h=6.626×1034J sh = 6.626 \times 10^{-34} \, \text{J s}
  • c=3×108m/sc = 3 \times 10^8 \, \text{m/s}
  • λ=550×109m\lambda = 550 \times 10^{-9} \, \text{m}
  • ϕCs=1.9eV\phi_{Cs} = 1.9 \, \text{eV}
  • ϕLi=2.5eV\phi_{Li} = 2.5 \, \text{eV}

Find: Which metal shows photoelectric emission.

Photon energy is given by

E=hcλE = \frac{hc}{\lambda}

Substituting the values,

E=6.626×1034×3×108550×109=3.613×1019JE = \frac{6.626\times10^{-34}\times3\times10^8}{550\times10^{-9}} = 3.613\times10^{-19} \, \text{J}

Convert this into electron volt using

1eV=1.602×1019J1 \, \text{eV} = 1.602\times10^{-19} \, \text{J}

So,

E=3.613×10191.602×1019=2.26eVE = \frac{3.613\times10^{-19}}{1.602\times10^{-19}} = 2.26 \, \text{eV}

Now compare:

  • For Cs, 2.26eV>1.9eV2.26 \, \text{eV} > 1.9 \, \text{eV}, so photoelectric effect occurs.
  • For Li, 2.26eV<2.5eV2.26 \, \text{eV} < 2.5 \, \text{eV}, so photoelectric effect does not occur.

Therefore, only Cs emits photoelectrons. The correct option is B.

Common mistakes

  • Comparing the wavelength directly with the work function is incorrect because wavelength and work function are different physical quantities. First convert the wavelength into photon energy, then compare that energy with the work function.

  • Assuming photoelectric effect occurs whenever light falls on the metal is wrong. Emission occurs only when the photon energy is greater than or equal to the work function of that specific metal.

  • Using the wrong inequality leads to the wrong conclusion. If E<ϕE < \phi, no photoelectric emission occurs; if E>ϕE > \phi, emission is possible.

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