MCQEasyJEE 2024Group 16 Elements

JEE Chemistry 2024 Question with Solution

The number of oxygen atoms present in the chemical formula of fuming sulfuric acid is:

  • A

    66

  • B

    77

  • C

    88

  • D

    99

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: The compound is fuming sulfuric acid.

Find: The number of oxygen atoms present in its chemical formula.

Fuming sulfuric acid is also known as oleum. It can be represented as H2S2O7H_2S_2O_7, or viewed as H2SO4+SO3H_2SO_4 + SO_3.

Counting oxygen atoms:

H2SO44 oxygen atomsH_2SO_4 \rightarrow 4 \text{ oxygen atoms} SO33 oxygen atomsSO_3 \rightarrow 3 \text{ oxygen atoms}

So, total oxygen atoms are

4+3=74 + 3 = 7

We can also verify directly from H2S2O7H_2S_2O_7, where the subscript of oxygen is 77.

Therefore, the number of oxygen atoms in fuming sulfuric acid is 77. Hence, the correct option is B.

Direct Formula Recognition

Given: Fuming sulfuric acid is oleum.

Find: The number of oxygen atoms in its formula.

Use the formula of oleum directly:

H2S2O7H_2S_2O_7

The subscript of oxygen is 77, so the compound contains 77 oxygen atoms.

Therefore, the correct option is B.

Common mistakes

  • Mistake: Confusing fuming sulfuric acid with only H2SO4H_2SO_4 and counting 44 oxygen atoms. Why it is wrong: fuming sulfuric acid is oleum, not pure sulfuric acid. What to do instead: recall that oleum is represented as H2S2O7H_2S_2O_7 or H2SO4+SO3H_2SO_4 + SO_3.

  • Mistake: Adding the formulas incorrectly and miscounting oxygen atoms. Why it is wrong: H2SO4H_2SO_4 contributes 44 oxygen atoms and SO3SO_3 contributes 33, giving 77, not any other value. What to do instead: count atoms from each part carefully before summing.

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