MCQEasyJEE 2024Salt Analysis (Cations & Anions)

JEE Chemistry 2024 Question with Solution

Number of metal ions characterized by flame test among the following: Sr2+\mathrm{Sr}^{2+}, Ba2+\mathrm{Ba}^{2+}, Ca2+\mathrm{Ca}^{2+}, Cu2+\mathrm{Cu}^{2+}, Zn2+\mathrm{Zn}^{2+}, Co2+\mathrm{Co}^{2+}, Fe2+\mathrm{Fe}^{2+}

  • A

    33

  • B

    44

  • C

    55

  • D

    66

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: The ions are Sr2+\mathrm{Sr}^{2+}, Ba2+\mathrm{Ba}^{2+}, Ca2+\mathrm{Ca}^{2+}, Cu2+\mathrm{Cu}^{2+}, Zn2+\mathrm{Zn}^{2+}, Co2+\mathrm{Co}^{2+} and Fe2+\mathrm{Fe}^{2+}.

Find: The number of metal ions that can be characterized by the flame test.

The flame test identifies metal ions that impart a distinct characteristic colour to the flame.

From the given analysis:

  • Sr2+\mathrm{Sr}^{2+} gives a bright red or crimson red flame.
  • Ba2+\mathrm{Ba}^{2+} gives a green or apple green flame.
  • Ca2+\mathrm{Ca}^{2+} gives an orange-red or brick red flame.
  • Cu2+\mathrm{Cu}^{2+} gives a blue-green flame.
  • Zn2+\mathrm{Zn}^{2+} does not give a useful characteristic flame colour.
  • Co2+\mathrm{Co}^{2+} does not give a useful characteristic flame colour.
  • Fe2+\mathrm{Fe}^{2+} does not give a useful characteristic flame colour for identification.

So, the ions characterized by flame test are Sr2+\mathrm{Sr}^{2+}, Ba2+\mathrm{Ba}^{2+}, Ca2+\mathrm{Ca}^{2+} and Cu2+\mathrm{Cu}^{2+}.

Hence, the total number is 44.

Therefore, the correct option is B.

Ion-wise Elimination

Given: A list of seven metal ions is provided.

Find: How many among them show characteristic flame colours.

Check each ion one by one:

  1. Sr2+\mathrm{Sr}^{2+} → characteristic flame colour present.
  2. Ba2+\mathrm{Ba}^{2+} → characteristic flame colour present.
  3. Ca2+\mathrm{Ca}^{2+} → characteristic flame colour present.
  4. Cu2+\mathrm{Cu}^{2+} → characteristic flame colour present.
  5. Zn2+\mathrm{Zn}^{2+} → no useful characteristic flame colour.
  6. Co2+\mathrm{Co}^{2+} → no useful characteristic flame colour.
  7. Fe2+\mathrm{Fe}^{2+} → no useful characteristic flame colour.

Thus, the count of ions identified by flame test is

44

Therefore, the correct option is B.

Common mistakes

  • Students often assume that every transition or metal ion gives a useful flame colour. This is incorrect because only some ions impart distinct characteristic colours. Check whether the flame colour is actually diagnostic.

  • A common mistake is counting Co2+\mathrm{Co}^{2+} or Fe2+\mathrm{Fe}^{2+} as characteristic in routine flame tests. Their colours are not reliably useful for identification here, so they should not be counted.

  • Some students include Zn2+\mathrm{Zn}^{2+} because it is a metal ion. Being a metal ion alone is not enough; the ion must produce a distinct visible flame colour.

Practice more Salt Analysis (Cations & Anions) questions

Get unlimited AI-adaptive practice, mastery tracking, and an AI tutor that explains every step — free to start.

Related questions