MCQEasyJEE 2024Concentration Terms (Molarity, Molality, etc.)

JEE Chemistry 2024 Question with Solution

If a substance ‘A’ dissolves in a solution of a mixture of ‘B’ and ‘C’ with their respective number of moles as nan_a, nbn_b, and ncn_c, the mole fraction of C in the solution is:

  • A

    Option 1

  • B

    Option 2

  • C

    Option 3

  • D

    Option 4

Answer

Correct answer:A

Step-by-step solution

Standard Method

Given: The number of moles of substances are nan_a, nbn_b, and ncn_c.

Find: The mole fraction of C in the solution.

The mole fraction of a component is defined as the ratio of the number of moles of that component to the total number of moles present in the solution.

So, the total number of moles is

na+nb+ncn_a + n_b + n_c

Therefore, the mole fraction of C is

XC=ncna+nb+ncX_C = \frac{n_c}{n_a + n_b + n_c}

Thus, the correct expression is ncna+nb+nc\frac{n_c}{n_a + n_b + n_c}. The solution states that the correct option is A. Since the listed options are only placeholders, the actual expression is not visible in the option text.

Definition-Based Explanation

Given: Substance A dissolves in a mixture containing B and C, with moles nan_a, nbn_b, and ncn_c.

Find: The mole fraction of component C.

By definition,

Mole fraction of a component=moles of that componenttotal moles of all components\text{Mole fraction of a component} = \frac{\text{moles of that component}}{\text{total moles of all components}}

Here, component C has ncn_c moles, and the total moles in the solution are

na+nb+ncn_a + n_b + n_c

Substituting into the definition,

XC=ncna+nb+ncX_C = \frac{n_c}{n_a + n_b + n_c}

Therefore, the mole fraction of C in the solution is ncna+nb+nc\frac{n_c}{n_a + n_b + n_c}, corresponding to option A according to the solution.

Common mistakes

  • Using only the moles of B and C in the denominator. This is wrong because mole fraction is calculated using the total moles of all components present in the solution. Always include na+nb+ncn_a + n_b + n_c in the denominator.

  • Putting the wrong component in the numerator. This is incorrect because the mole fraction of C must have ncn_c in the numerator. Always place the moles of the required component on top.

  • Using multiplication or subtraction of moles instead of addition. This is wrong because total moles are obtained by adding the moles of all components. Use the sum, not a product or difference.

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