NVAEasyJEE 2024Concentration Terms (Molarity, Molality, etc.)

JEE Chemistry 2024 Question with Solution

Volume of 3M3 \, \text{M} NaOH (formula weight 40g/mol40 \, \text{g/mol}) which can be prepared from 84g84 \, \text{g} of NaOH is x×101dm3x \times 10^{-1} \, \text{dm}^3.

Answer

Correct answer:7

Step-by-step solution

Standard Method

Given: Mass of NaOH = 84g84 \, \text{g}, molar mass of NaOH = 40g/mol40 \, \text{g/mol}, molarity = 3M3 \, \text{M}.

Find: The value of xx in x×101dm3x \times 10^{-1} \, \text{dm}^3.

First calculate the number of moles of NaOH:

nNaOH=8440=2.1n_{\text{NaOH}} = \frac{84}{40} = 2.1

Now use the molarity relation:

M=nVM = \frac{n}{V}

So,

V=nM=2.13=0.7LV = \frac{n}{M} = \frac{2.1}{3} = 0.7 \, \text{L}

Since 1L=1dm31 \, \text{L} = 1 \, \text{dm}^3, the volume is 0.7dm30.7 \, \text{dm}^3.

Expressing this in the required form:

0.7=7×1010.7 = 7 \times 10^{-1}

Therefore, the volume is 7×101dm37 \times 10^{-1} \, \text{dm}^3, so the answer is 77.

Using moles and molarity step-by-step

Given: Mass of NaOH = 84g84 \, \text{g}, formula weight = 40g/mol40 \, \text{g/mol}, required molarity = 3mol/L3 \, \text{mol/L}.

Find: The numerical value xx.

From the mass and molar mass,

nNaOH=massmolar mass=84g40g/mol=2.1moln_{\text{NaOH}} = \frac{\text{mass}}{\text{molar mass}} = \frac{84 \, \text{g}}{40 \, \text{g/mol}} = 2.1 \, \text{mol}

Using molarity,

M=nVsolM = \frac{n}{V_{\text{sol}}}

Rearranging,

Vsol=nNaOHM=2.13=0.7LV_{\text{sol}} = \frac{n_{\text{NaOH}}}{M} = \frac{2.1}{3} = 0.7 \, \text{L}

In scientific notation,

0.7L=7×101L0.7 \, \text{L} = 7 \times 10^{-1} \, \text{L}

Also, L\text{L} and dm3\text{dm}^3 are numerically equal.

Therefore, x=7x = 7. The correct answer is 7.

Common mistakes

  • Using 8484 directly as volume or molarity is incorrect because 84g84 \, \text{g} is the given mass, not the amount in moles. First convert mass to moles using n=mMn = \frac{m}{M}.

  • Substituting into the molarity formula incorrectly as V=MnV = \frac{M}{n} is wrong because molarity is defined as M=nVM = \frac{n}{V}. Rearranging correctly gives V=nMV = \frac{n}{M}.

  • Forgetting that 1L=1dm31 \, \text{L} = 1 \, \text{dm}^3 can lead to an unnecessary or incorrect conversion. Here 0.7L0.7 \, \text{L} is directly 0.7dm30.7 \, \text{dm}^3.

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