MCQEasyJEE 2024Group 13 Elements

JEE Chemistry 2024 Question with Solution

Given below are two statements: Assertion (A): Melting point of Boron (2453K2453 \, \text{K}) is unusually high in group 1313 elements. Reason (R): Solid Boron has very strong crystalline lattice. In the light of the above statements, choose the most appropriate answer from the options given below:

  • A

    Both (A) and (R) are correct but (R) is not the correct explanation of (A)

  • B

    Both (A) and (R) are correct and (R) is the correct explanation of (A)

  • C

    (A) is true but (R) is false

  • D

    (A) is false but (R) is true

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: Assertion (A): Melting point of Boron is 2453K2453 \, \text{K} and is unusually high in group 1313 elements.

Find: Whether Assertion (A) and Reason (R) are true, and whether Reason (R) correctly explains Assertion (A).

Boron has a much higher melting point than the other group 1313 elements, so Assertion (A) is true.

Solid boron has a strong crystalline covalent network lattice. Breaking this extensive lattice requires a large amount of energy, so Reason (R) is also true.

Since the strong crystalline lattice is the cause of the unusually high melting point, Reason (R) correctly explains Assertion (A).

Therefore, both (A) and (R) are correct and (R) is the correct explanation of (A). The correct option is B.

Detailed Logical Analysis

Given: Two statements about boron in group 1313 elements.

Find: The correct assertion-reason relationship.

  1. Examine Assertion (A): Boron has melting point 2453K2453 \, \text{K}, which is unusually high among group 1313 elements. So Assertion (A) is true.
  2. Examine Reason (R): Solid boron forms a very strong and complex three-dimensional covalent crystalline lattice. So Reason (R) is true.
  3. Check the explanation: A strong covalent lattice means many strong bonds must be broken for melting.
Strong covalent network    high energy required for melting    high melting point\text{Strong covalent network} \; \Rightarrow \; \text{high energy required for melting} \; \Rightarrow \; \text{high melting point}

Hence, Reason (R) correctly explains Assertion (A).

So, the correct answer is Both (A) and (R) are correct and (R) is the correct explanation of (A), that is, option B.

Common mistakes

  • Assuming that a high melting point in boron is due only to metallic character is incorrect because boron is not a typical metal in group 1313. Its unusually high melting point arises from its strong covalent crystalline network, so focus on bonding and lattice structure instead.

  • Treating the Reason (R) as merely an associated fact and not an explanation is wrong because the strong crystalline lattice directly causes the high melting point. Always check whether the reason gives the physical basis of the assertion.

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