NVAEasyJEE 2023Quantum Numbers

JEE Chemistry 2023 Question with Solution

The orbital angular momentum of an electron in a 3s3s orbital is xh2π\frac{x h}{2\pi}. The value of xx is _____ (nearest integer).

Answer

Correct answer:0

Step-by-step solution

Standard Method

Given: The orbital angular momentum of an electron in a 3s3s orbital is xh2π\frac{x h}{2\pi}.

Find: The value of xx.

The orbital angular momentum is given by

L=l(l+1)h2πL = \frac{\sqrt{l(l+1)}h}{2\pi}

For an ss-orbital, l=0l = 0. Substituting l=0l = 0,

L=0(0+1)h2π=0L = \frac{\sqrt{0(0+1)}h}{2\pi} = 0

Comparing with xh2π\frac{x h}{2\pi}, we get x=0x = 0.

Therefore, the value of xx is 00.

Common mistakes

  • Taking the principal quantum number n=3n = 3 as the angular momentum quantum number. This is wrong because orbital angular momentum depends on ll, not on nn. For a 3s3s orbital, use l=0l = 0.

  • Using the formula incorrectly as proportional to lh/2πl h/2\pi instead of l(l+1)h/2π\sqrt{l(l+1)}h/2\pi. This gives incorrect values for orbital angular momentum. Always substitute into the correct quantum mechanical expression.

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