MCQEasyJEE 2023Mole Concept

JEE Chemistry 2023 Question with Solution

1g1 \, \text{g} of a carbonate (M2CO3)\left(\text{M}_2\text{CO}_3\right) on treatment with excess HCl produces 0.01mol0.01 \, \text{mol} of CO2\text{CO}_2. The molar mass of M2CO3\text{M}_2\text{CO}_3 is _____

  • A

    100g/mol100 \, \text{g/mol}

  • B

    200g/mol200 \, \text{g/mol}

  • C

    250g/mol250 \, \text{g/mol}

  • D

    300g/mol300 \, \text{g/mol}

Answer

Correct answer:A

Step-by-step solution

Standard Method

Given: Mass of M2CO3\text{M}_2\text{CO}_3 is 1g1 \, \text{g} and moles of CO2\text{CO}_2 produced are 0.01mol0.01 \, \text{mol}.

Find: The molar mass of M2CO3\text{M}_2\text{CO}_3.

The reaction is

M2CO3+2HCl2MCl+H2O+CO2\text{M}_2\text{CO}_3 + 2\text{HCl} \rightarrow 2\text{MCl} + \text{H}_2\text{O} + \text{CO}_2

From the stoichiometry, 11 mole of M2CO3\text{M}_2\text{CO}_3 produces 11 mole of CO2\text{CO}_2.

Therefore,

moles of M2CO3=0.01mol\text{moles of } \text{M}_2\text{CO}_3 = 0.01 \, \text{mol}

Now,

Molar mass=massmoles=10.01=100g mol1\text{Molar mass} = \frac{\text{mass}}{\text{moles}} = \frac{1}{0.01} = 100 \, \text{g mol}^{-1}

Therefore, the molar mass is 100g mol1100 \, \text{g mol}^{-1} and the correct option is A.

Common mistakes

  • Assuming the mole ratio between M2CO3\text{M}_2\text{CO}_3 and CO2\text{CO}_2 is not 1:11:1. This is wrong because one carbonate ion gives one molecule of CO2\text{CO}_2. Use the balanced equation before calculating moles.

  • Using the formula molar mass=molesmass\text{molar mass} = \frac{\text{moles}}{\text{mass}} instead of massmoles\frac{\text{mass}}{\text{moles}}. This inverts the result. Always write the unit check to get g mol1\text{g mol}^{-1}.

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