MCQEasyJEE 2023System & Surroundings

JEE Chemistry 2023 Question with Solution

What happens when methane undergoes combustion in systems A and B respectively?

  • A

    System A: Temperature remains same \quad System B: Temperature rises

  • B

    System A: Temperature falls \quad System B: Temperature rises

  • C

    System A: Temperature falls \quad System B: Temperature remains same

  • D

    System A: Temperature rises \quad System B: Temperature remains same

Answer

Correct answer:A

Step-by-step solution

Standard Method

Given: Methane undergoes combustion in System A and System B.

Find: What happens to the temperature in the two systems.

From the solution text:

  1. System A (Adiabatic System): In an adiabatic system, there is no heat exchange with the surroundings. During the combustion of methane, the heat generated cannot escape. This results in an increase in temperature within the system.

  2. System B (Diathermic Container): In a diathermic container, heat can flow in and out of the system. During the combustion of methane, the heat generated escapes to maintain constant temperature.

Therefore, in System A, the temperature rises, while in System B, the temperature remains the same.

The solution concludes that the correct option is A, but this corresponds to the statement written as option D in the provided options. Based on the working, the defensible answer is D.

Common mistakes

  • Confusing adiabatic with constant temperature. Adiabatic means no heat exchange with surroundings, not fixed temperature. Here combustion releases heat inside the system, so temperature rises.

  • Assuming a diathermic container prevents heat transfer. This is incorrect because a diathermic boundary allows heat to pass, helping the system maintain constant temperature.

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