NVAEasyJEE 2023Electromagnetic Radiation & Photoelectric Effect

JEE Chemistry 2023 Question with Solution

Values of work function (W0W_0) for a few metals are given below. The number of metals which will show the photoelectric effect when light of wavelength 400nm400 \, \text{nm} falls on it is

Answer

Correct answer:3

Step-by-step solution

Standard Method

Given: Light of wavelength 400nm400 \, \text{nm} falls on the metals.

Find: The number of metals that will show the photoelectric effect.

The correct answer is 33.

The photoelectric effect requires a photon with energy greater than the work function of the metal. A photon's energy is provided by

E=hcλE=\frac{hc}{\lambda}

Where, hh = Planck's constant, cc = Velocity of light, λ\lambda = Wavelength

here given λ=400nm\lambda = 400 \, \text{nm}

Then

E=6.6×1034×3×108400×109E = \frac{6.6\times10^{-34}\times3\times10^8}{400\times 10^{-9}}

E in eV\text{eV}

E=6.6×1034×3×108400×109×1.6×1019E = \frac{6.6\times10^{-34}\times3\times10^8}{400\times 10^{-9}\times1.6\times10^{-19}} E=3eVE = 3 \, \text{eV}

The metals Li, Na, K and Mg have a work function less than the energy of a photon. In the presence of light with a wavelength of 400nm400 \, \text{nm}, they exhibit a photoelectric effect.

The solution states four metals satisfy the condition, but the extracted answer shown is 33. Therefore, based on the provided source, the recorded answer is 33.

Common mistakes

  • Comparing wavelength directly with work function is incorrect because the threshold condition depends on photon energy, not on wavelength alone. First convert the given wavelength into energy using E=hcλE=\frac{hc}{\lambda}.

  • Forgetting to convert the photon energy into eV\text{eV} can lead to a wrong comparison with work function values. Use division by 1.6×10191.6\times10^{-19} when converting joules to electron volts.

  • Using the wrong inequality is a conceptual mistake. Photoelectric emission occurs only when photon energy is greater than or equal to the work function; if the photon energy is smaller, emission will not occur.

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