MCQEasyJEE 2023Concentration Terms (Molarity, Molality, etc.)

JEE Chemistry 2023 Question with Solution

A solution is prepared by adding 2g2 \, \text{g} of "X" to 11 mole of water. Mass percent of "X" in the solution is _____.

  • A

    5%5\%

  • B

    20%20\%

  • C

    2%2\%

  • D

    10%10\%

Answer

Correct answer:D

Step-by-step solution

Standard Method

Given: Mass of solute X=2gX = 2 \, \text{g} and moles of solvent H2O=1\text{H}_2\text{O} = 1 mole.

Find: Mass percent of XX in the solution.

The molar mass of water is

18g/mol18 \, \text{g/mol}

So, mass of solvent is

1mol×18g/mol=18g1 \, \text{mol} \times 18 \, \text{g/mol} = 18 \, \text{g}

Total mass of solution is

2g+18g=20g2 \, \text{g} + 18 \, \text{g} = 20 \, \text{g}

Mass percent of XX is

% mass of X=Mass of XTotal mass×100=220×100=10%\%\text{ mass of } X = \frac{\text{Mass of } X}{\text{Total mass}} \times 100 = \frac{2}{20} \times 100 = 10\%

Therefore, the mass percent of XX in the solution is 10%10\%. The solution working gives this result, so the correct option is D. The solution shows option C, which disagrees with the actual calculation.

Common mistakes

  • Using 11 mole of water as if its mass were 1g1 \, \text{g} is incorrect because mole and gram are different quantities. First convert moles of water to mass using its molar mass 18g/mol18 \, \text{g/mol}.

  • Dividing by only the mass of solvent is incorrect because mass percent is based on total mass of solution. Add solute and solvent masses first to get 20g20 \, \text{g}.

  • Choosing the option from the solution without checking the calculation is incorrect here because the header label conflicts with the worked steps. Follow the numerical working and then map to the matching option.

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