MCQEasyJEE 2023Molecular Speeds (rms, Average, Most Probable)

JEE Physics 2023 Question with Solution

The temperature of an ideal gas is increased from 200K200 \, \text{K} to 800K800 \, \text{K}. If r.m.s. speed of gas at 200K200 \, \text{K} is v0v_0, then the r.m.s. speed of the gas at 800K800 \, \text{K} will be:

  • A

    4v04v_0

  • B

    2v02v_0

  • C

    v0v_0

  • D

    v04\frac{v_0}{4}

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: The temperature of an ideal gas changes from 200K200 \, \text{K} to 800K800 \, \text{K}. The r.m.s. speed at 200K200 \, \text{K} is v0v_0.

Find: The r.m.s. speed at 800K800 \, \text{K}.

Using

vrms=3RTmv_{\text{rms}} = \sqrt{\frac{3RT}{m}}

At 200K200 \, \text{K}, the r.m.s. speed is v0v_0:

v0=3R×200m(1)v_0 = \sqrt{\frac{3R \times 200}{m}} \quad \cdots (1)

At 800K800 \, \text{K}, the r.m.s. speed is vv':

v=3R×800m(2)v' = \sqrt{\frac{3R \times 800}{m}} \quad \cdots (2)

Dividing equation (2)(2) by equation (1)(1):

vv0=800200=4=2\frac{v'}{v_0} = \sqrt{\frac{800}{200}} = \sqrt{4} = 2

Therefore,

v=2v0v' = 2v_0

So, the correct option is B.

Common mistakes

  • Using a linear relation between r.m.s. speed and temperature is incorrect because vrmsTv_{\text{rms}} \propto \sqrt{T}, not TT. Use the square-root dependence before comparing speeds.

  • Substituting the temperatures and then forgetting to divide the new expression by the old one can lead to unnecessary algebra. Take the ratio vv0\frac{v'}{v_0} so the constants cancel directly.

  • Taking 800200=4\frac{800}{200} = 4 and concluding the speed becomes 4v04v_0 is wrong because the square root must still be applied. After simplification, evaluate 4=2\sqrt{4} = 2.

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