Sum of oxidation states of bromine in bromic acid and perbromic acid is _____.
JEE Chemistry 2023 Question with Solution
Answer
Correct answer:12
Step-by-step solution
Standard Method
Given: Bromic acid is and perbromic acid is .
Find: The sum of oxidation states of bromine in these two oxoacids.
For bromic acid, let the oxidation state of bromine be .
Thus, the oxidation state of bromine in bromic acid is .
For perbromic acid, let the oxidation state of bromine be .
Thus, the oxidation state of bromine in perbromic acid is .
Now, the required sum is
Therefore, the sum of oxidation states is .
Direct Oxoacid Trend
Given: The acids are and .
Find: The sum of oxidation states of Br.
In oxoacids, take and .
So for , bromine is , and for , bromine is .
Hence,
Therefore, the correct numerical answer is .
Common mistakes
Taking oxygen as instead of in these oxoacids gives the wrong oxidation state. In normal oxoacids, use unless a special exception is stated.
Forgetting that the molecule is neutral leads to an incorrect equation. The sum of oxidation states in and must be set equal to , not to a nonzero value.
Using the oxidation state from only one acid and not adding both values misses what the question asks. After finding Br in both acids, add and to get the required sum.
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