NVAEasyJEE 2023Oxidation Number & Redox Reactions

JEE Chemistry 2023 Question with Solution

Sum of oxidation states of bromine in bromic acid and perbromic acid is _____.

Answer

Correct answer:12

Step-by-step solution

Standard Method

Given: Bromic acid is HBrO3\text{HBrO}_3 and perbromic acid is HBrO4\text{HBrO}_4.

Find: The sum of oxidation states of bromine in these two oxoacids.

For bromic acid, let the oxidation state of bromine be xx.

x+(2×3)+1=0x + (-2 \times 3) + 1 = 0x6+1=0x - 6 + 1 = 0x=+5x = +5

Thus, the oxidation state of bromine in bromic acid is +5+5.

For perbromic acid, let the oxidation state of bromine be xx.

x+(2×4)+1=0x + (-2 \times 4) + 1 = 0x8+1=0x - 8 + 1 = 0x=+7x = +7

Thus, the oxidation state of bromine in perbromic acid is +7+7.

Now, the required sum is

5+7=125 + 7 = 12

Therefore, the sum of oxidation states is 1212.

Direct Oxoacid Trend

Given: The acids are HBrO3\text{HBrO}_3 and HBrO4\text{HBrO}_4.

Find: The sum of oxidation states of Br.

In oxoacids, take H=+1\text{H} = +1 and O=2\text{O} = -2.

So for HBrO3\text{HBrO}_3, bromine is +5+5, and for HBrO4\text{HBrO}_4, bromine is +7+7.

Hence,

+5++7=12+5 + +7 = 12

Therefore, the correct numerical answer is 1212.

Common mistakes

  • Taking oxygen as +2+2 instead of 2-2 in these oxoacids gives the wrong oxidation state. In normal oxoacids, use O=2\text{O} = -2 unless a special exception is stated.

  • Forgetting that the molecule is neutral leads to an incorrect equation. The sum of oxidation states in HBrO3\text{HBrO}_3 and HBrO4\text{HBrO}_4 must be set equal to 00, not to a nonzero value.

  • Using the oxidation state from only one acid and not adding both values misses what the question asks. After finding Br in both acids, add +5+5 and +7+7 to get the required sum.

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