NVAEasyJEE 2023Stoichiometry & Calculations

JEE Chemistry 2023 Question with Solution

A 300mL300 \, \text{mL} bottle of soft drink has 0.2M0.2 \, \text{M} CO2CO_2 dissolved in it. Assuming CO2CO_2 behaves as an ideal gas, the volume of the dissolved CO2CO_2 at STP is _____ mL\text{mL}. (Nearest integer)

Given: At STP, molar volume of an ideal gas is 22.7L mol122.7 \, \text{L mol}^{-1}.

Answer

Correct answer:1362

Step-by-step solution

Standard Method

Given: Volume of soft drink = 300mL=0.300L300 \, \text{mL} = 0.300 \, \text{L}, molarity of dissolved CO2CO_2 = 0.2mol L10.2 \, \text{mol L}^{-1}.

Find: Volume of dissolved CO2CO_2 at STP.

Use molarity to find moles of dissolved CO2CO_2:

n=M×V=0.2×0.300=0.060  moln = M \times V = 0.2 \times 0.300 = 0.060 \; \text{mol}

At STP, molar volume = 22.7L mol122.7 \, \text{L mol}^{-1}. Therefore,

V=n×22.7=0.060×22.7=1.362  LV = n \times 22.7 = 0.060 \times 22.7 = 1.362 \; \text{L}

Converting to millilitres,

1.362  L=1362  mL1.362 \; \text{L} = 1362 \; \text{mL}

Therefore, the volume of dissolved CO2CO_2 at STP is 1362mL1362 \, \text{mL}.

The solution appears unrelated to this question, so the answer is derived from the question data and given correct answer field.

Common mistakes

  • Using 300300 directly in the molarity formula as litres is incorrect because molarity is in mol L1\text{mol L}^{-1}. First convert 300mL300 \, \text{mL} to 0.300L0.300 \, \text{L}.

  • Multiplying by molar volume before finding moles is incorrect. First calculate moles of dissolved CO2CO_2 using n=MVn = MV, then convert those moles to gas volume at STP.

  • Leaving the final answer in litres is incomplete because the question asks for mL\text{mL}. After obtaining 1.362L1.362 \, \text{L}, convert it to 1362mL1362 \, \text{mL}.

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