MCQEasyJEE 2023Molecular Speeds (rms, Average, Most Probable)

JEE Physics 2023 Question with Solution

The root mean square velocity of molecules of gas is:

  • A

    Proportional to square root of temperature (T2T^2).

  • B

    Inversely proportional to square root of temperature (1T\frac{1}{\sqrt{T}}).

  • C

    Proportional to square root of temperature (T\sqrt{T}).

  • D

    Proportional to temperature (TT).

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: The question asks how root mean square velocity depends on temperature.

Find: The correct proportionality of vrmsv_{\text{rms}} with TT.

The solution states that the root mean square velocity is given by

vrms=3RTMv_{\text{rms}} = \sqrt{\frac{3RT}{M}}

where RR is the universal gas constant, TT is temperature in Kelvin, and MM is molar mass.

From this formula,

vrmsTv_{\text{rms}} \propto \sqrt{T}

Therefore, the root mean square velocity is proportional to the square root of temperature.

The solution concludes with "The Correct Option is B", but the worked relation vrmsTv_{\text{rms}} \propto \sqrt{T} matches option C in the listed options. Hence there is a discrepancy between the option label shown in the solution and the actual statement proved by the working. The defensible correct choice from the given options is C.

Discrepancy Note

The answer key says (3) and the solution working gives vrmsTv_{\text{rms}} \propto \sqrt{T}, both of which correspond to option C. However, the solution says "The Correct Option is B". Since the working is the primary source and clearly supports T\sqrt{T}, the conceptually correct answer is option C.

Common mistakes

  • A common mistake is confusing T\sqrt{T} with TT. This is wrong because the formula has temperature inside a square root. Use vrms=3RTMv_{\text{rms}} = \sqrt{\frac{3RT}{M}} and read the proportionality carefully.

  • Another mistake is choosing the inverse square root dependence 1T\frac{1}{\sqrt{T}}. This is incorrect because increasing temperature increases molecular speed, not decreases it. Check the direct dependence of TT inside the square root.

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