MCQEasyJEE 2023Diazonium Salts & Reactions

JEE Chemistry 2023 Question with Solution

Choose the correct colour of the product for the following reaction:

Reaction scheme showing a diazonium salt bearing OCOCH3 and SO3H substituents reacting with 1-Naphthyl amine to give a coupled product.
  • A

    Yellow

  • B

    White

  • C

    Red

  • D

    Blue

Answer

Correct answer:C

Step-by-step solution

Standard Method

Given: A diazonium salt reacts with 1-naphthyl amine.

Find: The correct colour of the product.

This is an example of a diazo coupling reaction, where a diazonium salt reacts with 1-naphthylamine to form an azo dye. The product is red in colour due to the extensive conjugation in the azo compound.

Therefore, the correct option is C.

Reaction Identification

The correct answer is (C) : Red.

Detailed reaction figure showing 1-naphthylamine coupling with an aromatic diazonium compound to form an azo product labeled SO3H and marked red in colour.

Common mistakes

  • Confusing the reaction with a simple substitution reaction is incorrect because this is specifically a diazo coupling reaction. Identify the azo dye formation first before deciding the product colour.

  • Assuming the product is colourless or white is incorrect because extensive conjugation in azo compounds usually gives strongly coloured products. Check for the presence of the N=N-N=N- linkage.

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